| Date | Time | Match | Type | Result |
| 8 Jul 2006 | 17:00 hrs | RKVV Erp - PSV | Vriendschappelijk | 0 - 6 |
| 12 Jul 2006 | 19:30 hrs | Panningen - PSV | Vriendschappelijk | 0 - 9 |
| 15 Jul 2006 | 20:00 hrs | KVSK United - PSV | Vriendschappelijk | 0 - 2 |
| 22 Jul 2006 | 19:00 hrs | FC Eindhoven - PSV | Vriendschappelijk | 0 - 4 |
| 25 Jul 2006 | 19:45 hrs | Stoke City - PSV | Vriendschappelijk | 0 - 0 |
| 29 Jul 2006 | 17:00 hrs | Newcastle United - PSV | Vriendschappelijk | 2 - 3 |
| 2 Aug 2006 | 19:00 hrs | Alemannia Aachen - PSV | Vriendschappelijk | 1 - 1 |
| 5 Aug 2006 | 15:00 hrs | 1.FC Nürnberg - PSV | Vriendschappelijk | 3 - 0 |
| 13 Aug 2006 | 18:00 hrs | PSV - Ajax | Johan Cruijff Schaal | 1 - 3 |
| 20 Aug 2006 | 14:30 hrs | PSV - NEC | Eredivisie | 3 - 1 |
| 27 Aug 2006 | 14:30 hrs | FC Twente - PSV | Eredivisie | 1 - 0 |
| 9 Sep 2006 | 19:30 hrs | Willem II - PSV | Eredivisie | 1 - 3 |
| 12 Sep 2006 | 20:45 hrs | PSV - Liverpool FC | Champions League | 0 - 0 |
| 17 Sep 2006 | 12:30 hrs | PSV - Feyenoord | Eredivisie | 2 - 1 |
| 20 Sep 2006 | 20:00 hrs | Kozakken Boys - PSV | KNVB Beker | 0 - 2 |
| 23 Sep 2006 | 19:30 hrs | ADO Den Haag - PSV | Eredivisie | 0 - 2 |
| 27 Sep 2006 | 20:45 hrs | Bordeaux - PSV | Champions League | 0 - 1 |
| 1 Oct 2006 | 14:30 hrs | sc Heerenveen - PSV | Eredivisie | 0 - 0 |
| 4 Oct 2006 | 19:00 hrs | STVV - PSV | Vriendschappelijk | 4 - 1 |
| 15 Oct 2006 | 14:30 hrs | PSV - Roda JC | Eredivisie | 4 - 1 |
| 18 Oct 2006 | 20:45 hrs | Galatasaray - PSV | Champions League | 1 - 2 |
| 22 Oct 2006 | 12:30 hrs | AZ - PSV | Eredivisie | 1 - 3 |
| 25 Oct 2006 | 20:00 hrs | PSV - Sparta | Eredivisie | 7 - 0 |
| 28 Oct 2006 | 20:00 hrs | RKC Waalwijk - PSV | Eredivisie | 0 - 3 |
| 31 Oct 2006 | 20:45 hrs | PSV - Galatasaray | Champions League | 2 - 0 |
| 4 Nov 2006 | 19:30 hrs | PSV - NAC Breda | Eredivisie | 3 - 0 |
| 9 Nov 2006 | 20:00 hrs | Vitesse - PSV | KNVB Beker | 0 - 4 |
| 12 Nov 2006 | 12:30 hrs | Ajax - PSV | Eredivisie | 0 - 1 |
| 18 Nov 2006 | 19:30 hrs | PSV - Excelsior | Eredivisie | 4 - 0 |
| 22 Nov 2006 | 20:45 hrs | Liverpool FC - PSV | Champions League | 2 - 0 |
| 25 Nov 2006 | 19:30 hrs | PSV - FC Utrecht | Eredivisie | 5 - 0 |
| 2 Dec 2006 | 20:00 hrs | Vitesse - PSV | Eredivisie | 0 - 1 |
| 5 Dec 2006 | 20:45 hrs | PSV - Bordeaux | Champions League | 1 - 3 |
| 9 Dec 2006 | 20:00 hrs | FC Groningen - PSV | Eredivisie | 0 - 2 |
| 15 Dec 2006 | 20:15 hrs | PSV - Heracles Almelo | Eredivisie | 3 - 0 |
| 23 Dec 2006 | 19:30 hrs | PSV - Willem II | Eredivisie | 4 - 0 |
| 26 Dec 2006 | 20:00 hrs | Feyenoord - PSV | Eredivisie | 1 - 1 |
| 30 Dec 2006 | 19:30 hrs | PSV - ADO Den Haag | Eredivisie | 2 - 1 |
| 14 Jan 2007 | 14:00 hrs | 1.FC Köln - PSV | Vriendschappelijk | 2 - 0 |
| 20 Jan 2007 | 19:30 hrs | PSV - sc Heerenveen | Eredivisie | 3 - 1 |
| 25 Jan 2007 | 20:45 hrs | PSV - Go Ahead Eagles | KNVB Beker | 3 - 2 |
| 28 Jan 2007 | 14:30 hrs | Roda JC - PSV | Eredivisie | 2 - 0 |
| 3 Feb 2007 | 19:30 hrs | PSV - AZ | Eredivisie | 2 - 3 |
| 11 Feb 2007 | 14:30 hrs | Sparta - PSV | Eredivisie | 1 - 1 |
| 17 Feb 2007 | 20:00 hrs | Heracles Almelo - PSV | Eredivisie | 0 - 2 |
| 20 Feb 2007 | 20:45 hrs | PSV - Arsenal FC | Champions League | 1 - 0 |
| 24 Feb 2007 | 19:30 hrs | PSV - FC Groningen | Eredivisie | 1 - 0 |
| 28 Feb 2007 | 20:45 hrs | NAC Breda - PSV | KNVB Beker | 3 - 0 |
| 3 Mar 2007 | 19:30 hrs | PSV - RKC Waalwijk | Eredivisie | 2 - 0 |
| 7 Mar 2007 | 20:45 hrs | Arsenal FC - PSV | Champions League | 1 - 1 |
| 11 Mar 2007 | 14:30 hrs | Excelsior - PSV | Eredivisie | 0 - 0 |
| 18 Mar 2007 | 14:30 hrs | PSV - Ajax | Eredivisie | 1 - 5 |
| 31 Mar 2007 | 19:30 hrs | NAC Breda - PSV | Eredivisie | 1 - 1 |
| 3 Apr 2007 | 20:45 hrs | PSV - Liverpool FC | Champions League | 0 - 3 |
| 7 Apr 2007 | 20:00 hrs | NEC - PSV | Eredivisie | 2 - 1 |
| 11 Apr 2007 | 20:45 hrs | Liverpool FC - PSV | Champions League | 1 - 0 |
| 14 Apr 2007 | 19:30 hrs | PSV - FC Twente | Eredivisie | 2 - 0 |
| 22 Apr 2007 | 14:30 hrs | FC Utrecht - PSV | Eredivisie | 1 - 1 |
| 29 Apr 2007 | 14:30 hrs | PSV - Vitesse | Eredivisie | 5 - 1 |
| 11 May 2007 | 14:30 hrs | FC Eindhoven - PSV | Vriendschappelijk | 1 - 5 |
| 19 May 2007 | 16:00 hrs | H.V.C.H. - PSV | Vriendschappelijk | 2 - 3 |
| 26 May 2007 | 17:00 hrs | V.V. Acht - PSV | Vriendschappelijk | 1 - 7 |
