| Date | Time | Match | Result |
| 23 Aug 2012 | 21:00 hrs | FC Zeta - PSV | 0 - 5 |
| 30 Aug 2012 | 19:00 hrs | PSV - FC Zeta | 9 - 0 |
| 20 Sep 2012 | 19:00 hrs | Dnjpr Dnjpropetrovsk - PSV | 2 - 0 |
| 4 Oct 2012 | 21:05 hrs | PSV - Napoli | 3 - 0 |
| 25 Oct 2012 | 21:05 hrs | PSV - AIK Stockholm | 1 - 1 |
| 8 Nov 2012 | 19:00 hrs | AIK Stockholm - PSV | 1 - 0 |
| 22 Nov 2012 | 21:05 hrs | PSV - Dnjpr Dnjpropetrovsk | 1 - 2 |
| 6 Dec 2012 | 19:00 hrs | Napoli - PSV | 1 - 3 |
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