| Date | Time | Match | Type | Result |
| 13 Jul 2005 | All Star-team Suwon - PSV | Vriendschappelijk | 0 - 1 | |
| 15 Jul 2005 | Seongnam Ilhwa - PSV | Vriendschappelijk | 1 - 2 | |
| 17 Jul 2005 | Once Caldas - PSV | Vriendschappelijk | 0 - 0 | |
| 20 Jul 2005 | Olympique Lyon - PSV | Vriendschappelijk | 1 - 1 | |
| 29 Jul 2005 | 19:30 hrs | Borussia M'Gladbach - PSV | Vriendschappelijk | 0 - 0 |
| 5 Aug 2005 | 20:30 hrs | Ajax - PSV | Johan Cruijff Schaal | 2 - 1 |
| 13 Aug 2005 | 19:30 hrs | Heracles Almelo - PSV | Eredivisie | 1 - 1 |
| 21 Aug 2005 | 14:30 hrs | PSV - Vitesse | Eredivisie | 2 - 1 |
| 28 Aug 2005 | 16:30 hrs | Roda JC - PSV | Eredivisie | 0 - 3 |
| 10 Sep 2005 | 19:30 hrs | PSV - FC Utrecht | Eredivisie | 1 - 0 |
| 13 Sep 2005 | 20:45 hrs | PSV - FC Schalke 04 | Champions League | 1 - 0 |
| 18 Sep 2005 | 16:30 hrs | FC Groningen - PSV | Eredivisie | 1 - 0 |
| 24 Sep 2005 | 19:30 hrs | PSV - RBC Roosendaal | Eredivisie | 2 - 0 |
| 28 Sep 2005 | 20:45 hrs | Fenerbahce SK - PSV | Champions League | 3 - 0 |
| 2 Oct 2005 | 16:30 hrs | SC Heerenveen - PSV | Eredivisie | 2 - 3 |
| 15 Oct 2005 | 19:30 hrs | PSV - AZ | Eredivisie | 3 - 0 |
| 19 Oct 2005 | 20:45 hrs | AC Milan - PSV | Champions League | 0 - 0 |
| 23 Oct 2005 | 12:30 hrs | PSV - Ajax | Eredivisie | 1 - 0 |
| 29 Oct 2005 | 20:00 hrs | FC Twente - PSV | Eredivisie | 0 - 1 |
| 1 Nov 2005 | 20:45 hrs | PSV - AC Milan | Champions League | 1 - 0 |
| 5 Nov 2005 | 19:30 hrs | PSV - Sparta | Eredivisie | 3 - 0 |
| 19 Nov 2005 | 20:00 hrs | RKC Waalwijk - PSV | Eredivisie | 4 - 4 |
| 23 Nov 2005 | 20:45 hrs | FC Schalke 04 - PSV | Champions League | 3 - 0 |
| 27 Nov 2005 | 14:30 hrs | PSV - ADO Den Haag | Eredivisie | 3 - 0 |
| 3 Dec 2005 | 19:30 hrs | PSV - NAC Breda | Eredivisie | 3 - 0 |
| 6 Dec 2005 | 20:45 hrs | PSV - Fenerbahce SK | Champions League | 2 - 0 |
| 11 Dec 2005 | 12:30 hrs | Feyenoord - PSV | Eredivisie | 1 - 0 |
| 17 Dec 2005 | 19:30 hrs | PSV - Willem II | Eredivisie | 4 - 1 |
| 20 Dec 2005 | 20:45 hrs | PSV - FC Twente | KNVB Beker | 3 - 0 |
| 26 Dec 2005 | 14:30 hrs | NEC - PSV | Eredivisie | 0 - 2 |
| 29 Dec 2005 | 18:00 hrs | PSV - FC Twente | Eredivisie | 1 - 1 |
| 15 Jan 2006 | 16:30 hrs | Sparta - PSV | Eredivisie | 0 - 1 |
| 20 Jan 2006 | 20:30 hrs | PSV - RKC Waalwijk | Eredivisie | 2 - 0 |
| 29 Jan 2006 | 12:30 hrs | ADO Den Haag - PSV | Eredivisie | 0 - 2 |
| 1 Feb 2006 | 20:45 hrs | FC Groningen - PSV | KNVB Beker | 2 - 3 |
| 4 Feb 2006 | 19:30 hrs | PSV - Roda JC | Eredivisie | 3 - 2 |
| 8 Feb 2006 | 20:00 hrs | FC Utrecht - PSV | Eredivisie | 1 - 2 |
| 11 Feb 2006 | 19:30 hrs | PSV - Heracles Almelo | Eredivisie | 1 - 0 |
| 17 Feb 2006 | 20:30 hrs | Vitesse - PSV | Eredivisie | 1 - 3 |
| 21 Feb 2006 | 20:45 hrs | PSV - Olympique Lyonnais | Champions League | 0 - 1 |
| 26 Feb 2006 | 12:30 hrs | AZ - PSV | Eredivisie | 1 - 2 |
| 4 Mar 2006 | 19:30 hrs | PSV - SC Heerenveen | Eredivisie | 4 - 1 |
| 8 Mar 2006 | 20:45 hrs | Olympique Lyonnais - PSV | Champions League | 4 - 0 |
| 11 Mar 2006 | 19:30 hrs | Ajax - PSV | Eredivisie | 0 - 0 |
| 18 Mar 2006 | 19:30 hrs | PSV - NEC | Eredivisie | 1 - 0 |
| 22 Mar 2006 | 19:00 hrs | PSV - AZ | KNVB Beker | 0 - 0 |
| 25 Mar 2006 | 19:30 hrs | Willem II - PSV | Eredivisie | 0 - 3 |
| 1 Apr 2006 | 19:30 hrs | RBC Roosendaal - PSV | Eredivisie | 1 - 2 |
| 9 Apr 2006 | 14:30 hrs | PSV - FC Groningen | Eredivisie | 1 - 1 |
| 12 Apr 2006 | 20:00 hrs | PSV - Feyenoord | Eredivisie | 1 - 1 |
| 16 Apr 2006 | 14:30 hrs | NAC Breda - PSV | Eredivisie | 2 - 6 |
| 28 Apr 2006 | 19:00 hrs | Hallescher FC - PSV | Vriendschappelijk | 0 - 3 |
| 7 May 2006 | 18:00 hrs | Ajax - PSV | KNVB Beker | 2 - 1 |