| Date | Time | Match | Result |
| 21 Jul 2021 | 21:00 hrs | PSV - Galatasaray | 5 - 1 |
| 28 Jul 2021 | 20:00 hrs | Galatasaray - PSV | 1 - 2 |
| 3 Aug 2021 | 20:00 hrs | PSV - FC Midtjylland | 3 - 0 |
| 10 Aug 2021 | 20:00 hrs | FC Midtjylland - PSV | 0 - 1 |
| 18 Aug 2021 | 21:00 hrs | Benfica - PSV | 2 - 1 |
| 24 Aug 2021 | 21:00 hrs | PSV - Benfica | 0 - 0 |
