| Date | Time | Match | Result |
| 8 Aug 2019 | 19:00 hrs | FK Haugesund - PSV | 0 - 1 |
| 15 Aug 2019 | 20:30 hrs | PSV - FK Haugesund | 0 - 0 |
| 22 Aug 2019 | 20:30 hrs | PSV - Apollon Limassol | 3 - 0 |
| 29 Aug 2019 | 19:00 hrs | Apollon Limassol - PSV | 0 - 4 |
| 19 Sep 2019 | 18:55 hrs | PSV - Sporting CP | |
| 3 Oct 2019 | 21:00 hrs | Rosenborg BK - PSV | |
| 24 Oct 2019 | 21:00 hrs | PSV - LASK Linz | |
| 7 Nov 2019 | 18:55 hrs | LASK Linz - PSV | |
| 28 Nov 2019 | 21:00 hrs | Sporting CP - PSV | |
| 12 Dec 2019 | 18:55 hrs | PSV - Rosenborg BK |